Does silver oxide react with hydrogen sulfide? Announcing the arrival of Valued Associate #679: Cesar Manara Planned maintenance scheduled April 23, 2019 at 23:30 UTC (7:30pm US/Eastern)Why Gold and Silver react minimally with atmosphere?Why do silver nitrate and sodium hydroxide react to produce silver(I) oxide?Why does magnesium oxide not react with water?Does mercury (I) chloride react with HCl?Why does calcium oxide react with sulfur dioxide?How does a group 15 oxide react with water?Does liquid ammonia react with hydrogen gas?How does CaO react with NaOH?does Hydrochloric Acid react with PET?Does aluminum oxide react with rubidium?

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Does silver oxide react with hydrogen sulfide?



Announcing the arrival of Valued Associate #679: Cesar Manara
Planned maintenance scheduled April 23, 2019 at 23:30 UTC (7:30pm US/Eastern)Why Gold and Silver react minimally with atmosphere?Why do silver nitrate and sodium hydroxide react to produce silver(I) oxide?Why does magnesium oxide not react with water?Does mercury (I) chloride react with HCl?Why does calcium oxide react with sulfur dioxide?How does a group 15 oxide react with water?Does liquid ammonia react with hydrogen gas?How does CaO react with NaOH?does Hydrochloric Acid react with PET?Does aluminum oxide react with rubidium?










3












$begingroup$


Electronic connectors are often silver plated. However, silver tarnishes fairly quickly and heavily. There exists a widespread misconception that the tarnishing of silver contacts is harmless, because silver oxide has about the same conductivity as silver itself. The problem however is that silver does not oxidize under normal conditions. The tarnish on the contacts is not silver oxide, but silver sulfide that develops due to the presence of some hydrogen sulfide in the air. Unlike silver oxide, silver sulfide is not a conductor, but a semiconductor with various potential adverse effects for the connection.



I have come across a reference that suggests oxidizing silver contacts before using them in order to prevent the development of the silver sulfide layer. This implies that silver oxide does not react with hydrogen sulfide in the air under normal conditions. Is this claim correct?



EDITS



I have corrected the typo by changing "sulfur dioxide" to "hydrogen sulfide" in the title and body of the question. Thanks for pointing this out in the answer!










share|improve this question









New contributor




safesphere is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.







$endgroup$
















    3












    $begingroup$


    Electronic connectors are often silver plated. However, silver tarnishes fairly quickly and heavily. There exists a widespread misconception that the tarnishing of silver contacts is harmless, because silver oxide has about the same conductivity as silver itself. The problem however is that silver does not oxidize under normal conditions. The tarnish on the contacts is not silver oxide, but silver sulfide that develops due to the presence of some hydrogen sulfide in the air. Unlike silver oxide, silver sulfide is not a conductor, but a semiconductor with various potential adverse effects for the connection.



    I have come across a reference that suggests oxidizing silver contacts before using them in order to prevent the development of the silver sulfide layer. This implies that silver oxide does not react with hydrogen sulfide in the air under normal conditions. Is this claim correct?



    EDITS



    I have corrected the typo by changing "sulfur dioxide" to "hydrogen sulfide" in the title and body of the question. Thanks for pointing this out in the answer!










    share|improve this question









    New contributor




    safesphere is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
    Check out our Code of Conduct.







    $endgroup$














      3












      3








      3





      $begingroup$


      Electronic connectors are often silver plated. However, silver tarnishes fairly quickly and heavily. There exists a widespread misconception that the tarnishing of silver contacts is harmless, because silver oxide has about the same conductivity as silver itself. The problem however is that silver does not oxidize under normal conditions. The tarnish on the contacts is not silver oxide, but silver sulfide that develops due to the presence of some hydrogen sulfide in the air. Unlike silver oxide, silver sulfide is not a conductor, but a semiconductor with various potential adverse effects for the connection.



      I have come across a reference that suggests oxidizing silver contacts before using them in order to prevent the development of the silver sulfide layer. This implies that silver oxide does not react with hydrogen sulfide in the air under normal conditions. Is this claim correct?



      EDITS



      I have corrected the typo by changing "sulfur dioxide" to "hydrogen sulfide" in the title and body of the question. Thanks for pointing this out in the answer!










      share|improve this question









      New contributor




      safesphere is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
      Check out our Code of Conduct.







      $endgroup$




      Electronic connectors are often silver plated. However, silver tarnishes fairly quickly and heavily. There exists a widespread misconception that the tarnishing of silver contacts is harmless, because silver oxide has about the same conductivity as silver itself. The problem however is that silver does not oxidize under normal conditions. The tarnish on the contacts is not silver oxide, but silver sulfide that develops due to the presence of some hydrogen sulfide in the air. Unlike silver oxide, silver sulfide is not a conductor, but a semiconductor with various potential adverse effects for the connection.



      I have come across a reference that suggests oxidizing silver contacts before using them in order to prevent the development of the silver sulfide layer. This implies that silver oxide does not react with hydrogen sulfide in the air under normal conditions. Is this claim correct?



      EDITS



      I have corrected the typo by changing "sulfur dioxide" to "hydrogen sulfide" in the title and body of the question. Thanks for pointing this out in the answer!







      inorganic-chemistry






      share|improve this question









      New contributor




      safesphere is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
      Check out our Code of Conduct.











      share|improve this question









      New contributor




      safesphere is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
      Check out our Code of Conduct.









      share|improve this question




      share|improve this question








      edited 39 mins ago







      safesphere













      New contributor




      safesphere is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
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      asked 3 hours ago









      safespheresafesphere

      1164




      1164




      New contributor




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      New contributor





      safesphere is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
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      Check out our Code of Conduct.




















          1 Answer
          1






          active

          oldest

          votes


















          3












          $begingroup$

          Silver sulfide is formed by Ag and hydrogen sulfide not sulfur dioxide. You need reducing conditions where the latter can be reduced to



          $$ceSO2 +reduction -> H2S$$



          Actually, sulfur dioxide chemisorbs on ultraclean silver surface, however heating can remove it. So this is reversible sorption, as suggested by Lassiter [1].



          Just note that Auger electron spectroscopy is done under extremely clean environment. There is no trace of water, oxygen or any other component! Real atmosphere is far more complicated and tons of photochemical reactions occur in the atmosphere. A typical indoor air has plenty of undesirable components. How does $ceSO2$ react with Ag must be another story because we cannot avoid or control other factors.



          Coming to the second part of the query: It is my speculation: If we have surface layer of silver oxide, will it prevent sulfide formation. In principle, possibly yes, because $ceAg2O$ is decent oxidizing agent. The moment traces of $ceH2S$ come in contact with the oxide, it will reduce the oxide to elemental silver, as per Franey et al. [2]:




          Polycrystalline silver has been exposed to the atmospheric gases $ceH2S$, $ceOCS$, $ceCS2$ and $ceSO2$ in humidified air under carefully controlled laboratory conditions. $ceOCS$ is shown to be an active corrodant while $ceCS2$ is quite inactive. At room temperature, the rates of sulfidation by $ceH2S$ and $ceOCS$ are comparable, and are more than an order of magnitude greater than those of $ceCS2$ and $ceSO2$. It appears that $ceOCS$ is the principal cause of atmospheric sulfidation of silver except near sources of $ceH2S$ where high concentrations may render the latter gas important. At constant absolute humidity, the sulfidation rate of
          silver by both H2S and OCS decreases from 20 to 40 °C and then increases to 40 to 80 °C.




          So may hydrogen sulfide may not be a major culprit!



          References



          1. Lassiter, W. S. Interaction of Sulfur Dioxide and Carbon Dioxide with Clean Silver in Ultrahigh Vacuum. J. Phys. Chem. 1972, 76 (9), 1289–1292. https://doi.org/10.1021/j100653a011.

          2. Franey, J. P.; Kammlott, G. W.; Graedel, T. E. The Corrosion of Silver by Atmospheric Sulfurous Gases. Corrosion Science 1985, 25 (2), 133–143. https://doi.org/10.1016/0010-938X(85)90104-0.





          share|improve this answer











          $endgroup$












          • $begingroup$
            Thanks for the correction, yes of course, hydrogen sulfide is exactly what I meant :) Please forget about sulfur dioxide, it was just a silly typo, sorry. I will edit the question momentarily. So, does silver oxide react with hydrogen sulfide? I am asking for a very practical purpose.
            $endgroup$
            – safesphere
            41 mins ago










          • $begingroup$
            Yes it does, almost instantaneously, especially if traces of water are present. Add a new paragraph in your question with a heading EDITS.
            $endgroup$
            – M. Farooq
            39 mins ago











          • $begingroup$
            Added, thanks! So the claim is wrong. Oxidizing silver contacts does not protect from silver sulfide developing on top (or in place) of silver oxide. Did I get this right? Thank you!
            $endgroup$
            – safesphere
            31 mins ago










          • $begingroup$
            I edited the answer.
            $endgroup$
            – M. Farooq
            19 mins ago











          Your Answer








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          1 Answer
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          1 Answer
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          active

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          active

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          active

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          3












          $begingroup$

          Silver sulfide is formed by Ag and hydrogen sulfide not sulfur dioxide. You need reducing conditions where the latter can be reduced to



          $$ceSO2 +reduction -> H2S$$



          Actually, sulfur dioxide chemisorbs on ultraclean silver surface, however heating can remove it. So this is reversible sorption, as suggested by Lassiter [1].



          Just note that Auger electron spectroscopy is done under extremely clean environment. There is no trace of water, oxygen or any other component! Real atmosphere is far more complicated and tons of photochemical reactions occur in the atmosphere. A typical indoor air has plenty of undesirable components. How does $ceSO2$ react with Ag must be another story because we cannot avoid or control other factors.



          Coming to the second part of the query: It is my speculation: If we have surface layer of silver oxide, will it prevent sulfide formation. In principle, possibly yes, because $ceAg2O$ is decent oxidizing agent. The moment traces of $ceH2S$ come in contact with the oxide, it will reduce the oxide to elemental silver, as per Franey et al. [2]:




          Polycrystalline silver has been exposed to the atmospheric gases $ceH2S$, $ceOCS$, $ceCS2$ and $ceSO2$ in humidified air under carefully controlled laboratory conditions. $ceOCS$ is shown to be an active corrodant while $ceCS2$ is quite inactive. At room temperature, the rates of sulfidation by $ceH2S$ and $ceOCS$ are comparable, and are more than an order of magnitude greater than those of $ceCS2$ and $ceSO2$. It appears that $ceOCS$ is the principal cause of atmospheric sulfidation of silver except near sources of $ceH2S$ where high concentrations may render the latter gas important. At constant absolute humidity, the sulfidation rate of
          silver by both H2S and OCS decreases from 20 to 40 °C and then increases to 40 to 80 °C.




          So may hydrogen sulfide may not be a major culprit!



          References



          1. Lassiter, W. S. Interaction of Sulfur Dioxide and Carbon Dioxide with Clean Silver in Ultrahigh Vacuum. J. Phys. Chem. 1972, 76 (9), 1289–1292. https://doi.org/10.1021/j100653a011.

          2. Franey, J. P.; Kammlott, G. W.; Graedel, T. E. The Corrosion of Silver by Atmospheric Sulfurous Gases. Corrosion Science 1985, 25 (2), 133–143. https://doi.org/10.1016/0010-938X(85)90104-0.





          share|improve this answer











          $endgroup$












          • $begingroup$
            Thanks for the correction, yes of course, hydrogen sulfide is exactly what I meant :) Please forget about sulfur dioxide, it was just a silly typo, sorry. I will edit the question momentarily. So, does silver oxide react with hydrogen sulfide? I am asking for a very practical purpose.
            $endgroup$
            – safesphere
            41 mins ago










          • $begingroup$
            Yes it does, almost instantaneously, especially if traces of water are present. Add a new paragraph in your question with a heading EDITS.
            $endgroup$
            – M. Farooq
            39 mins ago











          • $begingroup$
            Added, thanks! So the claim is wrong. Oxidizing silver contacts does not protect from silver sulfide developing on top (or in place) of silver oxide. Did I get this right? Thank you!
            $endgroup$
            – safesphere
            31 mins ago










          • $begingroup$
            I edited the answer.
            $endgroup$
            – M. Farooq
            19 mins ago















          3












          $begingroup$

          Silver sulfide is formed by Ag and hydrogen sulfide not sulfur dioxide. You need reducing conditions where the latter can be reduced to



          $$ceSO2 +reduction -> H2S$$



          Actually, sulfur dioxide chemisorbs on ultraclean silver surface, however heating can remove it. So this is reversible sorption, as suggested by Lassiter [1].



          Just note that Auger electron spectroscopy is done under extremely clean environment. There is no trace of water, oxygen or any other component! Real atmosphere is far more complicated and tons of photochemical reactions occur in the atmosphere. A typical indoor air has plenty of undesirable components. How does $ceSO2$ react with Ag must be another story because we cannot avoid or control other factors.



          Coming to the second part of the query: It is my speculation: If we have surface layer of silver oxide, will it prevent sulfide formation. In principle, possibly yes, because $ceAg2O$ is decent oxidizing agent. The moment traces of $ceH2S$ come in contact with the oxide, it will reduce the oxide to elemental silver, as per Franey et al. [2]:




          Polycrystalline silver has been exposed to the atmospheric gases $ceH2S$, $ceOCS$, $ceCS2$ and $ceSO2$ in humidified air under carefully controlled laboratory conditions. $ceOCS$ is shown to be an active corrodant while $ceCS2$ is quite inactive. At room temperature, the rates of sulfidation by $ceH2S$ and $ceOCS$ are comparable, and are more than an order of magnitude greater than those of $ceCS2$ and $ceSO2$. It appears that $ceOCS$ is the principal cause of atmospheric sulfidation of silver except near sources of $ceH2S$ where high concentrations may render the latter gas important. At constant absolute humidity, the sulfidation rate of
          silver by both H2S and OCS decreases from 20 to 40 °C and then increases to 40 to 80 °C.




          So may hydrogen sulfide may not be a major culprit!



          References



          1. Lassiter, W. S. Interaction of Sulfur Dioxide and Carbon Dioxide with Clean Silver in Ultrahigh Vacuum. J. Phys. Chem. 1972, 76 (9), 1289–1292. https://doi.org/10.1021/j100653a011.

          2. Franey, J. P.; Kammlott, G. W.; Graedel, T. E. The Corrosion of Silver by Atmospheric Sulfurous Gases. Corrosion Science 1985, 25 (2), 133–143. https://doi.org/10.1016/0010-938X(85)90104-0.





          share|improve this answer











          $endgroup$












          • $begingroup$
            Thanks for the correction, yes of course, hydrogen sulfide is exactly what I meant :) Please forget about sulfur dioxide, it was just a silly typo, sorry. I will edit the question momentarily. So, does silver oxide react with hydrogen sulfide? I am asking for a very practical purpose.
            $endgroup$
            – safesphere
            41 mins ago










          • $begingroup$
            Yes it does, almost instantaneously, especially if traces of water are present. Add a new paragraph in your question with a heading EDITS.
            $endgroup$
            – M. Farooq
            39 mins ago











          • $begingroup$
            Added, thanks! So the claim is wrong. Oxidizing silver contacts does not protect from silver sulfide developing on top (or in place) of silver oxide. Did I get this right? Thank you!
            $endgroup$
            – safesphere
            31 mins ago










          • $begingroup$
            I edited the answer.
            $endgroup$
            – M. Farooq
            19 mins ago













          3












          3








          3





          $begingroup$

          Silver sulfide is formed by Ag and hydrogen sulfide not sulfur dioxide. You need reducing conditions where the latter can be reduced to



          $$ceSO2 +reduction -> H2S$$



          Actually, sulfur dioxide chemisorbs on ultraclean silver surface, however heating can remove it. So this is reversible sorption, as suggested by Lassiter [1].



          Just note that Auger electron spectroscopy is done under extremely clean environment. There is no trace of water, oxygen or any other component! Real atmosphere is far more complicated and tons of photochemical reactions occur in the atmosphere. A typical indoor air has plenty of undesirable components. How does $ceSO2$ react with Ag must be another story because we cannot avoid or control other factors.



          Coming to the second part of the query: It is my speculation: If we have surface layer of silver oxide, will it prevent sulfide formation. In principle, possibly yes, because $ceAg2O$ is decent oxidizing agent. The moment traces of $ceH2S$ come in contact with the oxide, it will reduce the oxide to elemental silver, as per Franey et al. [2]:




          Polycrystalline silver has been exposed to the atmospheric gases $ceH2S$, $ceOCS$, $ceCS2$ and $ceSO2$ in humidified air under carefully controlled laboratory conditions. $ceOCS$ is shown to be an active corrodant while $ceCS2$ is quite inactive. At room temperature, the rates of sulfidation by $ceH2S$ and $ceOCS$ are comparable, and are more than an order of magnitude greater than those of $ceCS2$ and $ceSO2$. It appears that $ceOCS$ is the principal cause of atmospheric sulfidation of silver except near sources of $ceH2S$ where high concentrations may render the latter gas important. At constant absolute humidity, the sulfidation rate of
          silver by both H2S and OCS decreases from 20 to 40 °C and then increases to 40 to 80 °C.




          So may hydrogen sulfide may not be a major culprit!



          References



          1. Lassiter, W. S. Interaction of Sulfur Dioxide and Carbon Dioxide with Clean Silver in Ultrahigh Vacuum. J. Phys. Chem. 1972, 76 (9), 1289–1292. https://doi.org/10.1021/j100653a011.

          2. Franey, J. P.; Kammlott, G. W.; Graedel, T. E. The Corrosion of Silver by Atmospheric Sulfurous Gases. Corrosion Science 1985, 25 (2), 133–143. https://doi.org/10.1016/0010-938X(85)90104-0.





          share|improve this answer











          $endgroup$



          Silver sulfide is formed by Ag and hydrogen sulfide not sulfur dioxide. You need reducing conditions where the latter can be reduced to



          $$ceSO2 +reduction -> H2S$$



          Actually, sulfur dioxide chemisorbs on ultraclean silver surface, however heating can remove it. So this is reversible sorption, as suggested by Lassiter [1].



          Just note that Auger electron spectroscopy is done under extremely clean environment. There is no trace of water, oxygen or any other component! Real atmosphere is far more complicated and tons of photochemical reactions occur in the atmosphere. A typical indoor air has plenty of undesirable components. How does $ceSO2$ react with Ag must be another story because we cannot avoid or control other factors.



          Coming to the second part of the query: It is my speculation: If we have surface layer of silver oxide, will it prevent sulfide formation. In principle, possibly yes, because $ceAg2O$ is decent oxidizing agent. The moment traces of $ceH2S$ come in contact with the oxide, it will reduce the oxide to elemental silver, as per Franey et al. [2]:




          Polycrystalline silver has been exposed to the atmospheric gases $ceH2S$, $ceOCS$, $ceCS2$ and $ceSO2$ in humidified air under carefully controlled laboratory conditions. $ceOCS$ is shown to be an active corrodant while $ceCS2$ is quite inactive. At room temperature, the rates of sulfidation by $ceH2S$ and $ceOCS$ are comparable, and are more than an order of magnitude greater than those of $ceCS2$ and $ceSO2$. It appears that $ceOCS$ is the principal cause of atmospheric sulfidation of silver except near sources of $ceH2S$ where high concentrations may render the latter gas important. At constant absolute humidity, the sulfidation rate of
          silver by both H2S and OCS decreases from 20 to 40 °C and then increases to 40 to 80 °C.




          So may hydrogen sulfide may not be a major culprit!



          References



          1. Lassiter, W. S. Interaction of Sulfur Dioxide and Carbon Dioxide with Clean Silver in Ultrahigh Vacuum. J. Phys. Chem. 1972, 76 (9), 1289–1292. https://doi.org/10.1021/j100653a011.

          2. Franey, J. P.; Kammlott, G. W.; Graedel, T. E. The Corrosion of Silver by Atmospheric Sulfurous Gases. Corrosion Science 1985, 25 (2), 133–143. https://doi.org/10.1016/0010-938X(85)90104-0.






          share|improve this answer














          share|improve this answer



          share|improve this answer








          edited 3 mins ago









          andselisk

          19.7k665128




          19.7k665128










          answered 50 mins ago









          M. FarooqM. Farooq

          1,841111




          1,841111











          • $begingroup$
            Thanks for the correction, yes of course, hydrogen sulfide is exactly what I meant :) Please forget about sulfur dioxide, it was just a silly typo, sorry. I will edit the question momentarily. So, does silver oxide react with hydrogen sulfide? I am asking for a very practical purpose.
            $endgroup$
            – safesphere
            41 mins ago










          • $begingroup$
            Yes it does, almost instantaneously, especially if traces of water are present. Add a new paragraph in your question with a heading EDITS.
            $endgroup$
            – M. Farooq
            39 mins ago











          • $begingroup$
            Added, thanks! So the claim is wrong. Oxidizing silver contacts does not protect from silver sulfide developing on top (or in place) of silver oxide. Did I get this right? Thank you!
            $endgroup$
            – safesphere
            31 mins ago










          • $begingroup$
            I edited the answer.
            $endgroup$
            – M. Farooq
            19 mins ago
















          • $begingroup$
            Thanks for the correction, yes of course, hydrogen sulfide is exactly what I meant :) Please forget about sulfur dioxide, it was just a silly typo, sorry. I will edit the question momentarily. So, does silver oxide react with hydrogen sulfide? I am asking for a very practical purpose.
            $endgroup$
            – safesphere
            41 mins ago










          • $begingroup$
            Yes it does, almost instantaneously, especially if traces of water are present. Add a new paragraph in your question with a heading EDITS.
            $endgroup$
            – M. Farooq
            39 mins ago











          • $begingroup$
            Added, thanks! So the claim is wrong. Oxidizing silver contacts does not protect from silver sulfide developing on top (or in place) of silver oxide. Did I get this right? Thank you!
            $endgroup$
            – safesphere
            31 mins ago










          • $begingroup$
            I edited the answer.
            $endgroup$
            – M. Farooq
            19 mins ago















          $begingroup$
          Thanks for the correction, yes of course, hydrogen sulfide is exactly what I meant :) Please forget about sulfur dioxide, it was just a silly typo, sorry. I will edit the question momentarily. So, does silver oxide react with hydrogen sulfide? I am asking for a very practical purpose.
          $endgroup$
          – safesphere
          41 mins ago




          $begingroup$
          Thanks for the correction, yes of course, hydrogen sulfide is exactly what I meant :) Please forget about sulfur dioxide, it was just a silly typo, sorry. I will edit the question momentarily. So, does silver oxide react with hydrogen sulfide? I am asking for a very practical purpose.
          $endgroup$
          – safesphere
          41 mins ago












          $begingroup$
          Yes it does, almost instantaneously, especially if traces of water are present. Add a new paragraph in your question with a heading EDITS.
          $endgroup$
          – M. Farooq
          39 mins ago





          $begingroup$
          Yes it does, almost instantaneously, especially if traces of water are present. Add a new paragraph in your question with a heading EDITS.
          $endgroup$
          – M. Farooq
          39 mins ago













          $begingroup$
          Added, thanks! So the claim is wrong. Oxidizing silver contacts does not protect from silver sulfide developing on top (or in place) of silver oxide. Did I get this right? Thank you!
          $endgroup$
          – safesphere
          31 mins ago




          $begingroup$
          Added, thanks! So the claim is wrong. Oxidizing silver contacts does not protect from silver sulfide developing on top (or in place) of silver oxide. Did I get this right? Thank you!
          $endgroup$
          – safesphere
          31 mins ago












          $begingroup$
          I edited the answer.
          $endgroup$
          – M. Farooq
          19 mins ago




          $begingroup$
          I edited the answer.
          $endgroup$
          – M. Farooq
          19 mins ago










          safesphere is a new contributor. Be nice, and check out our Code of Conduct.









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          draft discarded


















          safesphere is a new contributor. Be nice, and check out our Code of Conduct.












          safesphere is a new contributor. Be nice, and check out our Code of Conduct.











          safesphere is a new contributor. Be nice, and check out our Code of Conduct.














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